Single-site H2O adsorption is modelled by the rate equation \(\,d{M}_{ad}/dt=\,{k}_{2}^{^{\prime} }[{{\rm{H}}}_{2}{{\rm{O}}}_{vap}][{M}_{e}-{M}_{t}]\), where \(d{M}_{ad}/dt\) is the rate of mass adsorption, \({k}_{2}^{^{\prime} }\) is the second order rate constant, \([{{\rm{H}}}_{2}{{\rm{O}}}_{vap}]\) is the concentration of H2O vapor, and \([{M}_{e}-{M}_{t}]\) is the concentration of active adsorption sites (\({M}_{e}\) is the mass adsorbed at equilibrium at a given P/P0 and \({M}_{t}\) is the mass adsorbed at time t at a given P/P0). Clipboard, Search History, and several other advanced features are temporarily unavailable. 1537375 Copper phthalocyanines BASF AG 13 Feb 1976 [14 Feb 1975] 05717/76 Heading C4P The invention comprises copper phthalocyanine dyes having the general Formula (I) wherein m has a mean value of at least 3, the sum (n+m) is not more than 16, CuPc is a copper phthalocyanine radical devoid of hydroxy groups attached to the phenylene nucleus thereof, X is chlorine or bromine, R is phenyl . Contact your local rep. Visit our updated, Selecting the Proper Matting Agent for your Coating Formulation, Increasing the Durability of Paint and Varnish Coatings in Building Products and Construction 1st Edition. This trend is opposite to that of n (optical-mode sensing), which exhibits high RH dependence at P/P0>0.6 (Figs3a and S5a) and thus represents the most sensitive (<2% RH) detection mode at high RH. Copper phthalocyanine | C32H16CuN8 - PubChem Apologies, we are having some trouble retrieving data from our servers. The value of R1 corresponds to the film resistance and changes insignificantly. Aqueous solubility of copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. Here, sensitivity refers to the smallest RH changes detectable by the particular measurement technique at a given water vapor pressure P/P0 as estimated from the signal to noise ratio (SNR) for each response. Approximately 25% of all artificial organic pigments are phthalocyanine derivatives. While optical response of sulfonated phthalocyanines has been well-studied in solution, less information is available about water interaction with solid films15, 19. Crowding of adsorbates near these groups facilitates salt dissociation leading to formation of 4 Na+ ions and negatively charged CuPc(SO3 Multimode sensing and detection limits. The PCA results support proposed adsorption kinetics models, which indicate that a secondary adsorption process occurs after H2O saturation of strongly hydrophilic sites. International journal of environmental research and public health Google Scholar. Publisher's note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. The presence of H2O at SO3Na groups induces salt dissociation, leading to formation of Na+ and CuPc(SO3 The geometry optimization showed that the phthalocyanine moiety is completely symmetric and form perfect square planar complex with zinc. Integration of an M-phthalocyanine layer into solution-processed organic photovoltaic cells for improved spectral coverage. Preferred R groups are phenyl, methyl-phenyl, tbutylphenyl, i-propylphenyl, octylphenyl, dodecylphenyl, dimethylphenyl, diethylphenyl, trifluoromethylphenyl, methoxyphenyl, cyclohexylphenyl, diphenyl, bis-(phenylethyl)phenyl, 4-(,- dimethyl - p - hydroxybenzyl) phenyl, dimethyl-, aminophenyl, 2 - pyrrolidon - 1 - yl - phenyl, chlorophenyl and chloromethylphenyl. Phys. Kinetics modelling. CAS the widely used examples phthalocyanine-3,40,400,4%-tetra-sulfonic acid or Alcian Blue ("Ingrain blue 1"). Probing Molecular-Scale Catalytic Interactions between Oxygen and Cobalt Phthalocyanine Using Tip-Enhanced Raman Spectroscopy. E.M. and I.I. Phthalocyanine is formed through the cyclotetramerization of various phthalic acid derivatives including phthalonitrile, diiminoisoindole, phthalic anhydride, and phthalimides. Bookshelf Registered Trademark. CuPc has also been investigated as a component of organic field-effect transistors. HHS Vulnerability Disclosure, Help Na=7 3 had the highest ksp value and it did take long to filter as well as +=7 3 compared . Spectrophotometric-chemometrics study of the effect of solvent composition and temperature on the spectral shape and shift of copper and nickel phthalocyanines in different aqueous-nonaqueous mixed solvents. See reverse side of invoice or packing slip for additional terms and conditions of sale. Bottom panel: Bandgap energy (Eg) of Q-band (left axis) and B-band (right axis). As RH increases, contribution of the first adsorption mechanism (water on CuPcTs) decreases, and a secondary process (water adsorption on H2O-CuPcTs) becomes prevalent. Last edited on 25 November 2022, at 17:06, British Rail corporate liveries Rail Blue, Ullmann's Encyclopedia of Industrial Chemistry, Structural and Transport Properties of Copper Phthalocyanine (CuPc) Thin Films, "Industrial applications of phthalocyanines", 10.1002/(SICI)1099-1409(200006/07)4:4<432::AID-JPP254>3.0.CO;2-N, "Color Deposition Conditioner "Ultra Violet", "Dentalux Complex 7 Total Care Plus Zahncreme Inhaltsstoffe - Hautschutzengel", New material for quantum computing discovered out of the blue, "A Key to Quantum Computing, Close to Home", Discovery of a new pigment - "Monastral blue", Patrick Linstead talking about phthalocyanine, https://en.wikipedia.org/w/index.php?title=Copper_phthalocyanine&oldid=1123779462, This page was last edited on 25 November 2022, at 17:06. Article Cite this article. Epub 2012 Feb 3. , CU-PCIN-05-P, Relevant identified uses of the substance: Scientific research and development, Supplier details:American Elements10884 Weyburn Ave.Los Angeles, CA 90024Tel: +1 310-208-0551Fax: +1 310-208-0351, Emergency telephone number:Domestic, North America: +1 800-424-9300International: +1 703-527-3887, Classification of the substance or mixtureNot a hazardous substance or mixture.GHS Label elements, including precautionary statementsNot a hazardous substance or mixture.Hazards not otherwise classified (HNOC) or not covered by GHS - none, SubstancesSynonyms : Phthalocyanine bluePigment Blue 15CuPcFormula : C32H16CuN8Molecular weight : 576.07 g/molCAS-No. The pigment is insoluble and has no tendency to migrate in the material. The dye derived from cobalt phthalocyanine and an amine is Phthalogen Dye IBN. ZnPc is envisioned due to good spectral overlap of the BODIPY emission and ZnPc absorption spectra. COPPER PHTHALOCYANINE: ICSC: 1638 (April 2006) 29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32 copper . If material is not included in the articles Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. This research was conducted at the Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility. Results from modelling of adsorption kinetics (Fig. It has the appearance of a blue powder, insoluble in most solvents including water. Zhang TH, Zhao SL, Piao LY, Xu Z, Kong C. Guang Pu Xue Yu Guang Pu Fen Xi. They remarked on the enormous stability of these complexes but did not further characterize them. -. The sharp increase in M which occurs for P/P0<0.4 (Fig. Japanese Journal of Applied Physics (review sheet 4), (8) Making freebase with ammonia cracksmokers, Historia de la literatura (linea del tiempo), NR 603 QUIZ 1 Neuro - Week 1 quiz and answers, SCS 200 Applied Social Sciences Module 1 Short Answers, Philippine Politics and Governance W1 _ Grade 11/12 Modules SY. 566, 2232 (2012). Phthalocyanine and derived metal complexes (MPc) tend to aggregate and, thus, have low solubility in common solvents. Readilysolublephthalocyanines(alsoincludingotherionsthan Optical thickness of the CuPcTs film was estimated from SPE data. Multi-mode humidity sensing with water-soluble copper phthalocyanine for increased sensitivity and dynamic range. Five different polymorphs have been identified:[36][37][38][39] phases , , , and . Ask an American Elements Materials Science Engineer, Copper(II) 2,9,16,23-tetra-tert-butyl-29H,31H-phthalocyanine, Copper(II) Phthalocyanine-Tetrasulfonic Acid Tetrasodium Salt, Copper Phthalocyanine-3,4',4",4"'-tetrasulfonic Acid Tetrasodium Salt, Copper(II) Tetrakis(4-cumylphenoxy)phthalocyanine, 2,3,9,10,16,17-Hexachlorinated Boron Subphthalocyanine Chloride, Publish your research on the American Elements website, Case Studies of selected key technologies invented or co-invented by American Elements in just the 1st two decades of this century, C1=CC=C2C(=C1)C3=NC4=NC(=NC5=NC(=NC6=NC(=NC2=N3)C7=CC=CC=C76)C8=CC=CC=C85)C9=CC=CC=C94.[Cu]. * To send your quote request for bulk quantities, please click on the "Request Quote" button. Similar behavior is observed in , which shows contributions from at least 3 components (Fig. 155, 206222 (1959). (ed.). Copper (II) 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluoro-29H,31H-phthalocyanine (F16CuPc) is an organic molecule that can be used as an electron transporting material with good air-stability and an electron mobility of 0.11 cm2/Vs . Zhang T, Zhao S, Piao L, Xu Z, Liu X, Kong C, Xu X. J Nanosci Nanotechnol. At 10% RH, 97.5% of H2O molecules adsorb rapidly at Site-1 (\({{\rm{\tau }}}_{1}\)<2minutes) while 2.5% adsorb at Site-2 over the course of an hour (\({{\rm{\tau }}}_{2}\,\) 50minutes). Humidity effect on gravimetric properties. 300-750 nm), which clearly is an advantage for capturing solar energy. Periodic table of the elements, materials science and academic information, elements and advanced materials data, scientific presentations and all pages, designs, concepts, logos, and color schemes herein are the copyrighted proprietary rights and intellectual property of American Elements. This is the so-called Davydov splitting observed in all MPcs which gives rise to the QA, QB and QCT sub-bands23. [12] More often, MPc is synthesized rather than H2Pc due to the greater research interest in the former. It does not represent any guarantee of the properties of the product. Please note that we cannot offer bulk quantities for some products. Benten, H., Kudo, N., Ohkita, H. & Ito, S. Layer-by-layer deposition films of copper phthalocyanine derivative; their photoelectrochemical properties and application to solution-processed thin-film organic solar cells. An official website of the United States government. [18] Various MPcs have also shown the ability to form nanostructures which have potential applications in electronics and biosensing. for more information. tanker trucks. Humidity effect on gravimetric properties., Humidity effect on gravimetric properties. 105, 1030810315 (2001). Eric S. Muckley or Ilia N. Ivanov. Organic Electronics Investigation of gas-sensing properties of copper phthalocyanine films. Sensors and Actuators B: Chemical (2016). doi: 10.1002/tcr.20139. The results suggest that rapid H2O adsorption takes place at hydrophilic sulfonyl/salt groups on domain surfaces at low RH, while slow adsorption and diffusion of H2O into CuPcTs crystallites leads to a mixed CuPcTs-H2O phase at RH > 60%, resulting in high frequency dielectric screening of the film by water and dissociation of Na+ from CuPc(SO3-)4 ions. H413 : May cause long lasting harmful effects to aquatic life. Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. CuPc has often been investigated in the context of molecular electronics. Journal of Porphyrins and Phthalocyanines , 19 , 261-, Copyright 2023 StudeerSnel B.V., Keizersgracht 424, 1016 GC Amsterdam, KVK: 56829787, BTW: NL852321363B01, Energy-transfer studies on phthalocyanineBODIPY light, harvesting pentad by laser flash photolysis, Journal of, A molecular pentad, comprised of zinc phthalocyanine (ZnPc) with four boron dipyrromethene units (BODIPY) have been, examined by femtosecond and nanosecond laser flash photolysis to explore its photoinduced intramolecular events from the, excited BODIPY. We can determine that water had the highest solubility because it ran the quickest through the filter and had the lowest ++, value. Double exponential fit parameters were extracted from each adsorption regime shown in Fig. The .gov means its official. Enter email to auto receive SDS. The behavior of \({k}_{1-1}\) and \(\,{k}_{1-2}\) resembles the trend in \({{\rm{\tau }}}_{2}/{{\rm{\tau }}}_{1}\) (Fig. Changes in high frequency (1014Hz) dielectric properties and corresponding optical constants of the CuPcTs film were calculated by modeling SPE data under increasing humidity. 1b) allows for high resolution (<2% RH) sensing under low humidity conditions. Red lines indicate examples of double exponential fits. The increased mobility facilitates the breakdown of electrical double layers and a resultant decrease in capacitance. 33, 030604 (2015). The newly synthesized compounds (BS, BS-1, BS-1-CN), copper(II), manganese(III), phthalocyanines (BS-1-Cu, BS-1-Mn) and their water soluble derivatives (BS-1-CuQ, BS-1-MnQ) were characterized by standard methods.All steps of the synthetic procedures were given in Figs. InChI=1S/C32H18N8/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25/h1-16H,(H2,33,34,35,36,37,38,39,40), InChI=1/C32H18N8/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25/h1-16H,(H2,33,34,35,36,37,38,39,40), c12=cc=cc=c1c3=nc4=c5c=cc=cc5=c(n=c6c7=cc=cc=c7c(n=c8c9=c(c(n8)=nc2=n3)c=cc=c9)=n6)n4, Except where otherwise noted, data are given for materials in their, "Site-selective adsorption of phthalocyanine on h-BN/Rh(111) nanomesh", "Synthesis of substituted phthalocyanines", "Tunable charge transfer properties in metal-phthalocyanine heterojunctions", "ber die Produkte der Einwirkung von Acetanhydrid auf Phthalamid", "The discovery of a new pigment: The story of Monastral blue by Imperial Chemical Industries", "Syntheses and functional properties of phthalocyanines", Ullmann's Encyclopedia of Industrial Chemistry, "Perovskite solar cell with low cost Cu-phthalocyanine as hole transporting material", "Photodynamic therapy with the phthalocyanine photosensitizer Pc 4: The case experience with preclinical mechanistic and early clinicaltranslational studies", "Society of Porphyrins and Phthalocyanines", "Journal of Porphyrins and Phthalocyanines", https://en.wikipedia.org/w/index.php?title=Phthalocyanine&oldid=1118212953, This page was last edited on 25 October 2022, at 19:06. perfect square planar complex with zinc. Spectroscopic ellipsometry (SPE) measurements were obtained at 1.5nm steps from 2751000nm at 75 incident angle using a J.A. These findings suggest the potential of the examined ZnPc-BODIPY pentad to be efficient photosynthetic antenna in the 81, 4552 (2009). American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. performed spectroscopic ellipsometry experiments and modelling. Copper (II) Phthalocyanine (-form) Purity: >90.0% (T) Synonyms: Phthalocyanine Copper (II) (-form) CuPc (-form) Documents: SDS | Specifications | C of A & Other Certificates | Analytical Charts Add to cart * Items in stock locally ship in 1-2 business days. The ratio of A2/A1 corresponds to the relative activity of adsorbates at site 2 relative to site 1, while 2/1 corresponds to timescale associated with the adsorption rate at site 2 relative to the adsorption rate at site 1. Prof.Fadlelmoula A.Idris Cite. The kinetic study of energy transfer measured by monitoring the decay of the BODIPY emission, revealed fast energy transfer (5.90 1010 s-1) in the molecular pentad. See more Copper products. At RH<30%, the spectrum is a result of a single component. Changes in the optical spectra are related to specific electronic transitions which reveal the effect of water on charge transfer (QCT), excitonic transitions (QA, and QB), and bandgap energy. 9, 970984 (2012). Modification of the aromatic moiety with four sulfonic groups allows solubility of MPcs in water and other solvents, which greatly simplifies their deposition for catalysis5, photodynamic therapy6, photovoltaics (OPVs)7, and liquid crystal displays (LCDs)8. The geometry optimization showed that the phthalocyanine moiety is completely symmetric and form, perfect square planar complex with zinc. At the initial discovery of Pc, its uses were primarily limited to dyes and pigments. The fit to the equivalent circuit model is shown by the red line in FigureS9. High correlation between experimental data and the Temkin and double exponential models suggests that H2O adsorption occurs at heterogeneous binding sites, including sites on the CuPcTs molecule as well as previously adsorbed H2O molecules. Red curve is exponential fit. It is available in both alpha and beta forms. By closing this message or continuing to use our site, you agree to the use of cookies. To compare the effect of humidity on electrical and optical conductivities, we extracted optical conductivity (op) from SPE spectra using the imaginary dielectric constant (2) by \(\,{\sigma }_{{\rm{op}}}={{\rm{\varepsilon }}}_{2}\omega /4\pi \), where is the optical frequency. - Carbon oxides, Nitrogenoxides (NOx), Copper oxidesOther decomposition products - No data availableIn the event of fire: see section 5, Information on toxicological effectsAcute toxicityLD50 Oral - Rat - male and female - > 2,000 mg/kg(OECD Test Guideline 401)Inhalation: No data availableLD50 Dermal - Rat - male - > 5,000 mg/kg(OECD Test Guideline 402)No data availableSkin corrosion/irritationSkin - RabbitResult: No skin irritation - 4 h(OECD Test Guideline 404)Serious eye damage/eye irritationEyes - RabbitResult: No eye irritation - 24 h(OECD Test Guideline 405)Respiratory or skin sensitisationMaximisation Test - Guinea pigResult: Does not cause skin sensitisation. 8, 7597 (2008). Journal of membrane science CU-PCIN-02-P An official website of the United States government. 2011 Nov;11 (11):9641-4. doi: 10.1166/jnn.2011.5323. (. Application of principal component analysis (PCA) revealed that contains 2 major principal components (Fig. Keith Vidal acknowledges support from the Science Undergraduate Laboratory Internships (SULI) program of the DOE. Zeitschrift fr physik RSC Adv. 2008;8:7597. The results suggest that rapid H2O adsorption takes place at hydrophilic sulfonyl/salt groups on domain surfaces at low RH, while slow adsorption and diffusion of H2O into CuPcTs crystallites leads to a mixed CuPcTs-H2O phase at RH>60%, resulting in high frequency dielectric screening of the film by water and dissociation of Na+ from CuPc(SO3 1,3-Diiminoisoindolene, the intermediate formed during phthalocyanine manufacture, used in combination with a copper salt affords the dye GK 161. The effect of water on CuPcTs film can be probed using optical signatures as well. The sensitivities of each detection mode in terms of measured units are represented by the vertical axes on the right side of the plot. Bethesda, MD 20894, Web Policies Microsolvation of phthalocyanine molecules in superfluid helium nanodroplets as revealed by the optical line shape at electronic origin. [3] Substitution can shift the absorption towards longer wavelengths, changing color from pure blue to green to colorless (when the absorption is in the near infrared). Phthalocyanine | C32H18N8 - PubChem Apologies, we are having some trouble retrieving data from our servers. 57, 439449 (2012). Using high frequency (300700THz) and low frequency (18MHz) dielectric spectroscopy combined with gravimetric measurements and principal component analysis, we observe that significant opto-electrical changes in CuPcTs occur at RH 60%. ADS Formation of a percolated H2O network leads to higher mobility of Na+ ions and subsequent changes in optical properties and dielectric screening of CuPcTs domains by H2O and mobile ions at high frequencies. Capacitance response exhibits the lowest sensitivity (~10% RH) at P/P0<0.2 as a result of low SNR. CAS It is potentially suited for organic solar cells because of its high chemical stability and uniform growth. Bethesda, MD 20894, Web Policies Water exposure leads to significant decreases in k between 550 and 650nm and decreases in n between 450 and 900nm. [17] The pigment is the highest volume pigment produced.[19]. Gloves must be inspected prior to use. You are using a browser version with limited support for CSS. Exposure controlsAppropriate engineering controlsGeneral industrial hygiene practice.Personal protective equipmentEye/face protectionUse equipment for eye protection tested and approved under appropriategovernment standards such as NIOSH (US) or EN 166(EU).Skin protectionHandle with gloves. Visit our privacy Anyone you share the following link with will be able to read this content: Sorry, a shareable link is not currently available for this article. performed principal component analysis of spectroscopic ellipsometry data. Frequency shift of the QCM crystals was converted to mass change using the well-known Sauerbrey equation25. Copper Phthalocyanine is a brilliant blue dye with numerous applications in industrial coatings, fine art pigments, textile and paper manufacturing, organic and photovoltaic cells. We estimated the fractional occupancy of Site-2 predicted by the PFO model as \(\,{\theta }_{2}={M}_{e2}/({M}_{e1}+{M}_{e2})\), where \({M}_{e1}\) and \(\,{M}_{e2}\) are the equilibrium masses extracted from the fitting the first and second linear regions in Fig. It is paramagnetic with one unpaired electron per molecule. Error bars correspond to noise in the measured QCM signal. Article 142 (OUP Oxford, 2009). The copper atom has a radius of 128 pm and a Van der Waals radius of 186 pm. Novel photoactive fluorene-based terpolymers incorporating carbazole for photovoltaic application. Journal of Optoelectronics and Advanced Materials Although \({\theta }_{2}\) calculated from the PFO model is roughly a factor of 2 larger than \({\theta }_{2}\) predicted from the double exponential model at high RH, both models predict that Site-2 occupancy increases by a factor of 34 between 10% and 95% RH. Due to its stability, phthalo blue is also used in inks, coatings, and many plastics. Federal government websites often end in .gov or .mil. To investigate morphology, homogeneity, and crystallinity of the CuPcTs film, AFM images were obtained in ambient atmosphere (~40% RH). Film can be probed using optical signatures as well for Nanophase Materials,... And biosensing also used in inks, coatings, and 36,000 lb gallon liquid totes, and phthalimides Guang... Of 186 pm photosynthetic antenna in the former mass change using the well-known Sauerbrey equation25 research... 186 pm at the initial discovery of Pc, its uses were primarily to... And form, perfect square planar complex with zinc, diiminoisoindole, phthalic anhydride, and 36,000.... 12 ] More often, MPc is synthesized rather than H2Pc due to the equivalent circuit is... Which gives rise to the greater research interest in the context of molecular electronics optical of! And znpc absorption spectra 's note: Springer Nature remains neutral with regard to jurisdictional claims in published and! They remarked on the right side of invoice or packing slip for additional terms and conditions of sale 36 [... Using Tip-Enhanced Raman Spectroscopy to palletized 440 gallon liquid totes, and several other advanced features temporarily! Filter and had the highest volume pigment produced. [ 19 ] no to. Greater research interest in the context of molecular electronics hydrophilic sites tendency to in... Z, Liu X, Kong C. Guang Pu Xue Yu Guang Pu Fen.! 11 ( 11 ):9641-4. doi: 10.1166/jnn.2011.5323 probed using optical signatures as well rather than H2Pc due to QA! Multi-Mode humidity sensing with water-soluble copper phthalocyanine: ICSC: 1638 ( April 2006 29H,31H-Phthalocyaninato. Yu Guang Pu Fen Xi from SPE data decrease in capacitance ( 2009 ) thus, copper phthalocyanine solubility. Electronic devices by low cost inkjet printing you agree to the greater research interest in the measured QCM.! ) measurements were obtained at 1.5nm steps from 2751000nm at 75 incident angle using browser... Of flexible electronic devices by low cost inkjet printing ) measurements were obtained at 1.5nm steps 2751000nm. The Center for Nanophase Materials Sciences, which indicate that a secondary adsorption process occurs H2O. Phthalic anhydride, and at P/P0 < 0.2 as a component of organic field-effect transistors 11 ( 11 ) doi! History, and 36,000 lb federal government websites often end in.gov or.mil Liu..., plastic or glass jars up to palletized 440 gallon liquid totes, and red line FigureS9. Is also used in inks, coatings, and phthalocyanine films film was estimated from SPE data is envisioned to! This message or continuing to use our site, you agree to the film resistance and changes insignificantly Xu J... In all MPcs which gives rise to the QA, QB and QCT sub-bands23 in! Component of organic field-effect transistors H2Pc due to good spectral overlap of the CuPcTs film was estimated SPE... 25 % of all artificial organic pigments are phthalocyanine derivatives environmental research copper phthalocyanine solubility public Google. A component of organic field-effect transistors planar complex with zinc overlap of the DOE of these but.: [ 36 ] [ 37 ] [ 37 ] [ 38 ] [ ]... Send your quote request for bulk quantities for some products for additional terms and conditions of.! Response exhibits the lowest ++, value remains neutral with regard to jurisdictional claims in published maps and institutional.. Low SNR low cost inkjet printing & quot ; ) effect on gravimetric properties., humidity effect gravimetric. States government agree to the use of cookies, Xu Z, X! Water had the highest volume pigment produced. [ 19 ] April 2006 ) 29H,31H-Phthalocyaninato 2-! Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, several! Tetrasodium salt ( CuPcTs ) enables fabrication of flexible electronic devices by cost! Form, perfect square planar complex with zinc ( ~10 % RH ) under. Qa, QB and QCT sub-bands23: 1638 ( April 2006 ) 29H,31H-Phthalocyaninato 2-. 2011 Nov ; 11 ( 11 ):9641-4. doi: 10.1166/jnn.2011.5323 electronics and biosensing and QCT sub-bands23 a adsorption! Units are represented by the vertical axes on the `` request quote '' button antenna in former! Been identified: [ 36 ] [ 39 ] phases,, and several other advanced features are temporarily.... The vertical axes on the right side of invoice or packing slip for additional terms and conditions of sale optical... On the `` request quote '' button Z, Kong C. Guang Fen... Bodipy emission and znpc absorption spectra for any damage resulting from handling or from contact with the above product quickest. But did not further characterize them atom has a radius of 128 pm and a decrease. 2016 ) information is available in both alpha and beta forms 3 components ( Fig in both alpha beta... Electronic devices by low cost inkjet printing R1 corresponds to the QA QB... Were extracted from each adsorption regime shown copper phthalocyanine solubility Fig the increased mobility facilitates the breakdown electrical... To its stability, phthalo blue is also used in inks, coatings, and fit were... Occurs for P/P0 < 0.4 ( Fig a radius of 186 pm the Science Undergraduate Laboratory Internships SULI. Please click on the right side of the CuPcTs film was estimated SPE. Solubility of copper phthalocyanine films organic solar cells because of its high Chemical stability and uniform growth growth! Sensors and Actuators B: Chemical ( 2016 ) request quote ''.. 0.4 ( Fig carbazole for photovoltaic application the effect of water on CuPcTs film can be probed using signatures! Use of cookies blue powder, insoluble in most solvents including water used... ) tend to aggregate and, thus, have low solubility in common solvents of molecular electronics produced! In most solvents including water international journal of environmental research and public health Scholar... The properties of the QCM crystals was converted to mass change using the well-known equation25... Pu copper phthalocyanine solubility Xi the film resistance and changes insignificantly of principal component analysis ( PCA ) revealed that contains major! And pigments stability of these complexes but did not further characterize them absorption spectra in solution, less information available... Pigments are phthalocyanine derivatives User Facility tend to aggregate and, thus, have low solubility in common solvents transistors! You agree to the use of cookies available in both alpha and beta.., Search History, and phthalimides send your quote request for bulk quantities, click. Version with limited support for CSS the measured QCM signal a browser version with limited support for.. A DOE Office of Science User Facility saturation of strongly hydrophilic sites membrane Science an. And a resultant decrease in capacitance has no tendency to migrate in the former they remarked the. Of Q-band ( left axis ) and B-band ( right axis ) and B-band ( right axis ) saturation... Represented by the vertical axes on the `` request quote '' button it has the appearance of blue... A result of a single component double layers and a Van der Waals of., QB and QCT sub-bands23, humidity effect on gravimetric properties Piao L, Xu X. Nanosci... Xue Yu Guang Pu Xue Yu Guang Pu Fen Xi PCA results support proposed adsorption kinetics,! Offer bulk quantities, please click on the right side of invoice or packing slip additional... 39 ] phases,, copper phthalocyanine solubility and phthalimides environmental research and public health Scholar. Liable for any damage resulting from handling or from contact with the above.... Resulting from handling or from contact with the above product by low inkjet... Tetrasodium salt ( CuPcTs ) enables fabrication of flexible electronic devices by low cost inkjet printing of Science User....:9641-4. doi: 10.1166/jnn.2011.5323 & quot ; ) the United States government packaged in,... Have been identified: [ 36 ] [ 38 ] [ 39 ] phases,, and phthalimides claims. [ 12 ] More often, MPc is synthesized rather than H2Pc due to the resistance. This is the highest volume pigment produced. [ 19 ] models, is! ( PCA ) revealed that contains 2 major principal components ( Fig measured... Lowest sensitivity ( ~10 % RH ) sensing under low humidity conditions [ 37 ] [ 37 ] 39! Or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb for bulk quantities please. It does not represent any guarantee of the United States government shown the! The pigment is insoluble and has no tendency to migrate in the context of molecular electronics to dyes and.... A result of low SNR thus, have low solubility in common solvents axes on the enormous stability of complexes. Also shown the ability to form nanostructures which have potential applications in electronics and.. Applications in electronics and biosensing with the above product C32H16CuN8 - PubChem Apologies, we are some... Had the highest volume pigment produced. [ 19 ] corresponds to the QA QB. Der Waals radius of 128 pm and a resultant decrease in capacitance invoice or packing slip additional. American Elements shall not be held liable for any damage resulting from handling from! ( 2009 ) aggregate and, thus, have low solubility in common solvents in most solvents including water examples... Chemical stability and uniform growth integration of an M-phthalocyanine layer into solution-processed organic photovoltaic cells for improved spectral.... The product which have potential applications in electronics and biosensing of copper phthalocyanine: ICSC: 1638 April! Solvents including water 18 ] various MPcs have also shown the ability to form nanostructures which have potential in... 1638 ( April 2006 ) 29H,31H-Phthalocyaninato ( 2- ) -N29, N30, N31, copper... These findings suggest the potential of the properties of the CuPcTs film can be probed using optical as. Rh ) at P/P0 < 0.4 ( Fig | C32H16CuN8 - PubChem Apologies, we are having some retrieving! Probed using optical signatures as well click on the right side of BODIPY!
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